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Polypeptide Organic Radical Batteries: A Sustainable Frontier in Energy Storage by TP Nguyen·2021·Cited by 372—Here we demonstrate a metal-free,polypeptide-based battery, in which viologens and nitroxide radicals are incorporated as redox-active groups along polypeptide 

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Polypeptide organic radical batteries by TP Nguyen·2021·Cited by 372—Here we demonstrate a metal-free,polypeptide-based battery, in which viologens and nitroxide radicals are incorporated as redox-active groups along polypeptide 

The quest for sustainable and environmentally friendly energy storage solutions has led researchers to explore novel materials and chemistries. Among the most promising advancements are polypeptide organic radical batteries, a groundbreaking technology that leverages the unique properties of polypeptides to create metal-free and recyclable batteries. This innovative approach, highlighted in a 2021 Nature publication, signifies a major leap forward in the field of organic radical batteries.

At the core of these polypeptide organic radical batteries lies the ingenious incorporation of redox-active groups, such as viologens and nitroxide radicals, along the polypeptide backbone. This design allows the polypeptides themselves to function as both cathode and anode materials, eliminating the need for traditional, often scarce and toxic, metal components. This all-polypeptide organic radical battery concept addresses critical challenges in current battery technology, offering a more sustainable and eco-conscious alternative.

The significance of this development is underscored by the pursuit of all-organic radical batteries, which aim to replace conventional battery chemistries with abundant and earth-friendly materials. The polypeptide-based battery architecture offers a unique advantage due to the inherent biodegradability and recyclability of polypeptides. This means that at the end of their lifecycle, these batteries can be safely degraded and their components reused, minimizing environmental impact. This aligns with the growing demand for natural and organic materials in technological applications.

Research has demonstrated that these polypeptide batteries are not only environmentally sound but also exhibit promising electrochemical performance. The incorporation of polypeptides provides a versatile platform for designing materials with tailored properties. For instance, a self-assembly strategy using a lipopeptide additive has been explored to synergistically enhance ion transport and interfacial stability within the battery, further improving its efficiency and longevity.

The development of polypeptide organic radical batteries is part of a broader trend in the field of organic radical batteries, which are gaining traction as a viable alternative to lithium-ion and other metal-based systems. The ability to create metal-free energy storage devices is particularly crucial, given concerns about the environmental and ethical implications of metal mining. Moreover, the flexibility and potential for low-cost manufacturing of organic electrode materials make them attractive for a wide range of applications, from portable electronics to grid-scale energy storage.

The polypeptide organic radical batteries represent a significant step towards achieving truly sustainable energy storage. By harnessing the power of polypeptides and organic radicals, researchers are paving the way for a future where energy solutions are not only efficient but also in harmony with the environment. The ongoing research into these batteries and related organic radical systems promises further innovations in this exciting and rapidly evolving field. The concept of an all-organic Na-ion battery, while a different approach, also highlights the broader movement towards metal-free energy storage.

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by J Lutkenhaus·2022—4). Published in Nature May 2021, we reported the first-everpolypeptide organic radical batteriesthat could degrade on-command. The redox 

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